Thiourea bridged periodic mesoporous organosilica with ultra-small Pd nanoparticles for coupling reactions

Doustkhah, Esmail, Rostamnia, Sadegh, Imura, Masataka, Ide, Yusuke, Mohammadi, Shiva, Hyland, Christopher J. T., You, Jungmok, Tsunoji, Nao, Zeynizadeh, Behzad and Yamauchi, Yusuke (2017) Thiourea bridged periodic mesoporous organosilica with ultra-small Pd nanoparticles for coupling reactions. RSC Advances, 7 89: 56306-56310. doi:10.1039/c7ra11711f


Author Doustkhah, Esmail
Rostamnia, Sadegh
Imura, Masataka
Ide, Yusuke
Mohammadi, Shiva
Hyland, Christopher J. T.
You, Jungmok
Tsunoji, Nao
Zeynizadeh, Behzad
Yamauchi, Yusuke
Title Thiourea bridged periodic mesoporous organosilica with ultra-small Pd nanoparticles for coupling reactions
Journal name RSC Advances   Check publisher's open access policy
ISSN 2046-2069
Publication date 2017-01-01
Sub-type Article (original research)
DOI 10.1039/c7ra11711f
Open Access Status Not yet assessed
Volume 7
Issue 89
Start page 56306
End page 56310
Total pages 5
Publisher Royal Society of Chemistry
Language eng
Subject 1600 Chemistry
1500 Chemical Engineering
Abstract A synthesis of thiourea-bridged mesoporous organosilica is reported. Using transmission electron microscopy, low-angle XRD measurements and N adsorption-desorption isotherms the formation of a highly ordered mesoporous structure with a high surface area (>400 m g) has been confirmed. Deposition of Pd nanoparticles inside the mesopores resulted in a material that showed excellent catalytic activity in a Suzuki-coupling reaction and retained this activity over several consecutive runs.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sun, 31 Dec 2017, 20:48:29 EST