Synthesis and X-ray crystal structure of the cobalt(III) complex of 6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane (atac), cis-[(Co(atac)Cl2]ClO4· 1 2H2O

Donlevy, Therese M., Gahan, Lawrence R. and Hambley, Trevor W. (1993) Synthesis and X-ray crystal structure of the cobalt(III) complex of 6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane (atac), cis-[(Co(atac)Cl2]ClO4· 1 2H2O. Polyhedron, 12 13: 1593-1597. doi:10.1016/S0277-5387(00)87067-9


Author Donlevy, Therese M.
Gahan, Lawrence R.
Hambley, Trevor W.
Title Synthesis and X-ray crystal structure of the cobalt(III) complex of 6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane (atac), cis-[(Co(atac)Cl2]ClO4· 1 2H2O
Journal name Polyhedron   Check publisher's open access policy
ISSN 0277-5387
Publication date 1993-01-01
Sub-type Article (original research)
DOI 10.1016/S0277-5387(00)87067-9
Open Access Status Not yet assessed
Volume 12
Issue 13
Start page 1593
End page 1597
Total pages 5
Language eng
Subject 1606 Physical and Theoretical Chemistry
1604 Inorganic Chemistry
2505 Materials Chemistry
Abstract The crystal structure of cis-[Co(atac)Cl]ClO· 1 2HO [atac = 6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane] has been determined by X-ray diffraction methods. The tetradentate ligand atac contains the NS donor set and is coordinated to cobalt(III) through a secondary amine and a thioether in the cycloheptane ring, and through a pendant primary amine. The chloro ligands coordinated in a cis arrangement make up the octahedral environment of the metal ion.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Fri, 29 Dec 2017, 07:56:11 EST