A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes

HEILMAYER, W, DALVI, TS, KAPPE, CO, WENTRUP, C, GRUBER, K, STERK, H and KOLLENZ, G (1995) A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes. Journal of the Chemical Society-Chemical Communications, 7: 797-798. doi:10.1039/c39950000797


Author HEILMAYER, W
DALVI, TS
KAPPE, CO
WENTRUP, C
GRUBER, K
STERK, H
KOLLENZ, G
Title A convenient de novo synthesis of functionalised 2,4,6,8- tetraoxaadamantanes
Journal name Journal of the Chemical Society-Chemical Communications   Check publisher's open access policy
ISSN 0022-4936
Publication date 1995-01-01
Year available 1995
Sub-type Article (original research)
DOI 10.1039/c39950000797
Open Access Status Not yet assessed
Issue 7
Start page 797
End page 798
Total pages 2
Place of publication CAMBRIDGE
Publisher ROYAL SOC CHEMISTRY
Language eng
Abstract Trioxabicyclononadienes 2 and 4, easily obtained by addition of nucleophiles to the stable alpha-oxoketene 1, are transformed into the corresponding 2,4,6,8-tetraoxaadamantanes 3 and 5 in high yields by acid-catalysed hydrolysis.
Keyword Bridged Bis-Dioxines
Dipivaloylketene
Dimerization
Nucleophiles
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
 
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