Crystal structure, and the infrared and Raman spectra, of potassium, hydroxylamine-N,O-disulphonate, K2[O3SONHSO3]. The infrared and Raman spectra of potassium hydroxylaminetrisulphonate sesquihydrate, K3[O3SON(SO3) 2]·1.5H2O

Hall, John R., Johnson, Robert A., Kennard, Colin H. L., Smith, Graham, Skelton, Brian W. and White, Allan H. (1980) Crystal structure, and the infrared and Raman spectra, of potassium, hydroxylamine-N,O-disulphonate, K2[O3SONHSO3]. The infrared and Raman spectra of potassium hydroxylaminetrisulphonate sesquihydrate, K3[O3SON(SO3) 2]·1.5H2O. Journal of the Chemical Society, Dalton Transactions, 11: 2199-2207. doi:10.1039/DT9800002199


Author Hall, John R.
Johnson, Robert A.
Kennard, Colin H. L.
Smith, Graham
Skelton, Brian W.
White, Allan H.
Title Crystal structure, and the infrared and Raman spectra, of potassium, hydroxylamine-N,O-disulphonate, K2[O3SONHSO3]. The infrared and Raman spectra of potassium hydroxylaminetrisulphonate sesquihydrate, K3[O3SON(SO3) 2]·1.5H2O
Journal name Journal of the Chemical Society, Dalton Transactions
ISSN 1472-7773
Publication date 1980-01-01
Sub-type Article (original research)
DOI 10.1039/DT9800002199
Open Access Status Not yet assessed
Issue 11
Start page 2199
End page 2207
Total pages 9
Language eng
Subject 1600 Chemistry
Abstract The crystal structure of K[OSONHSO] has been determined using three-dimensional X-ray diffraction data with 1 097 observed reflections. Crystals are monoclinic, space group P2/a, with Z = 4 in a cell of dimensions a = 11.009(3), b = 10.040(2), c = 7.483(3) Å, and β = 109.49(2)°. The structure was solved by the heavy-atom method and refined by full-matrix least squares to R 0.033. The N-S bond [1.704(3) Å] is markedly longer than found for K[NH(SO )] in which both sulphonate groups are bound directly to nitrogen. The infrared (4 000-50 cm) and Raman spectra of K [OSONHSO] and K[O SON(SO)]·1.5HO and their N and H derivatives at 77 K are reported and interpreted. Aqueous spectra have also been recorded. The following frequencies were assigned; ν(N-O), 925; ν(N-S), 808; and ν[S-O(N)], ca. 730 cm for K[OSONHSO]; ν(N-O), 930; ν(N-S), 820; ν (N-S), 757; and ν [S-O(N)], 708 cm for K[OSON(SO )]·1.5HO.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
 
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