Silver(I) Phenoxyalkanoates: The Crystal and Molecular Structures of catena-[Bis-μ-(phenoxyacetato-0, 0′)- disilver(I)] and Bis[bis-μ-(4-fluoro- phenoxyacetato-O, O)-bis(aquasiIver(I))]

Smith G., Sagatys D.S., Campbell C.A., Lynch D.E. and Kennard C.H.L. (1990) Silver(I) Phenoxyalkanoates: The Crystal and Molecular Structures of catena-[Bis-μ-(phenoxyacetato-0, 0′)- disilver(I)] and Bis[bis-μ-(4-fluoro- phenoxyacetato-O, O)-bis(aquasiIver(I))]. Australian Journal of Chemistry, 43 10: 1707-1712. doi:10.1071/CH9901707


Author Smith G.
Sagatys D.S.
Campbell C.A.
Lynch D.E.
Kennard C.H.L.
Title Silver(I) Phenoxyalkanoates: The Crystal and Molecular Structures of catena-[Bis-μ-(phenoxyacetato-0, 0′)- disilver(I)] and Bis[bis-μ-(4-fluoro- phenoxyacetato-O, O)-bis(aquasiIver(I))]
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1990-01-01
Sub-type Article (original research)
DOI 10.1071/CH9901707
Volume 43
Issue 10
Start page 1707
End page 1712
Total pages 6
Language eng
Subject 1600 Chemistry
Abstract The crystal structures of the silver(I) complexes with phenoxyacetic acid and 4- fluorophenoxyacetic acid, catena-[bis-μ-(phenoxyacetato-O, O′)-disilver(i)] (1) and bis[bis-μ-(4- fluorophenoxyacetato-O, O′)-(aquasilver(1))] (2) have been determined and refined to residuals R 0•068 and 0•036 respectively for 1783 and 2549 observed reflections. Both structures are based on similar bis(carboxylato-O, O′) bridged dimers with Ag-Ag 2•866(2) A (1) and 2•836(2) Å (2). However, (1) forms a step polymer through terminal oxygens [Ag-O 2•417, 2•443(9) Å], while (2) is a discrete centrosymmetric tetramer with a water molecule on each of the four silver atoms [Ag-Ow 2 - 499(4) A], and an Ag-O bridge distance of 2•498(4) A. This results in triangular coordination about one silver and tetrahedral about the second. Experimental data indicate that anhydrous silver(I) 4-chlorophenoxyacetate (3) is similar to complex (1).
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
Versions
Version Filter Type
Citation counts: Scopus Citation Count Cited 26 times in Scopus Article | Citations
Google Scholar Search Google Scholar
Created: Tue, 08 Aug 2017, 00:10:50 EST by System User