A configurational model for siphonariid polypropionates derived from structural and biosynthetic considerations

Garson M.J., Goodman J.M. and Paterson I. (1994) A configurational model for siphonariid polypropionates derived from structural and biosynthetic considerations. Tetrahedron Letters, 35 37: 6929-6932. doi:10.1016/0040-4039(94)85044-5


Author Garson M.J.
Goodman J.M.
Paterson I.
Title A configurational model for siphonariid polypropionates derived from structural and biosynthetic considerations
Journal name Tetrahedron Letters   Check publisher's open access policy
ISSN 0040-4039
Publication date 1994-09-01
Sub-type Article (original research)
DOI 10.1016/0040-4039(94)85044-5
Open Access Status Not yet assessed
Volume 35
Issue 37
Start page 6929
End page 6932
Total pages 4
Language eng
Subject 1303 Biochemistry
3002 Drug Discovery
1605 Organic Chemistry
Abstract The energies of the acetal ring systems in siphonarin B (2), muamvatin (5), and caloundrin B (7) are compared. A configurational model for siphonariid metabolites is proposed which rationalises the stereochemistry of their acyclic precursors. It contains a tetrapropionate unit common to the Cane-Celmer-Westley PAPA model for polyether antibiotics of bacterial origin.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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