The preparation and crystal structure of ammonium bis(glycolato) antimony (III), the first structurally characterised discrete monomeric four-coordinate complex of antimony (III) with a dianionic a-hydroxy acid

Smith G. and Kennard C.H.L. (1996) The preparation and crystal structure of ammonium bis(glycolato) antimony (III), the first structurally characterised discrete monomeric four-coordinate complex of antimony (III) with a dianionic a-hydroxy acid. Main Group Chemistry, 1 2: 175-177. doi:10.1080/13583149612331338395


Author Smith G.
Kennard C.H.L.
Title The preparation and crystal structure of ammonium bis(glycolato) antimony (III), the first structurally characterised discrete monomeric four-coordinate complex of antimony (III) with a dianionic a-hydroxy acid
Journal name Main Group Chemistry   Check publisher's open access policy
ISSN 1745-1167
Publication date 1996-01-01
Sub-type Article (original research)
DOI 10.1080/13583149612331338395
Open Access Status Not yet assessed
Volume 1
Issue 2
Start page 175
End page 177
Total pages 3
Language eng
Subject 1605 Organic Chemistry
1604 Inorganic Chemistry
2505 Materials Chemistry
Abstract The antimony (III) complex with the α-hydroxy acid glycolic acid (hydroxyacetic acid), ammonium bis(hydroxyacetato) antimony (III), has been prepared and its structure determined by X-ray diffraction. The novel monomeric complex anion involves two glycolato(2-) ligands in bidentate coordination with the typical distorted pseudo trigonal bipyramidal stereochemistry about Sb. Bond lengths are Sb-O(axial = carboxyl), 2.136(4), 2.200(5)Å and Sb-O (equatorial = hydroxyl), 1.980(5), 1.985(4)Å.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
Versions
Version Filter Type
Citation counts: Scopus Citation Count Cited 1 times in Scopus Article | Citations
Google Scholar Search Google Scholar
Created: Tue, 25 Jul 2017, 00:03:52 EST by System User