Metal-(phenylthio)acetic acid interactions-VI. The crystal and molecular structures of diaquabis[(phenylsulfinyl) acetato[bis(pyridine)copper(II) and bis[(benzylthio) acetato]bis(pyridine)copper(II)

Hong Chang W., Mak T.C.W., Smith G., O'Reilly E.J. and Kennard C.H.L. (1985) Metal-(phenylthio)acetic acid interactions-VI. The crystal and molecular structures of diaquabis[(phenylsulfinyl) acetato[bis(pyridine)copper(II) and bis[(benzylthio) acetato]bis(pyridine)copper(II). Polyhedron, 4 8: 1443-1448. doi:10.1016/S0277-5387(00)86978-8


Author Hong Chang W.
Mak T.C.W.
Smith G.
O'Reilly E.J.
Kennard C.H.L.
Title Metal-(phenylthio)acetic acid interactions-VI. The crystal and molecular structures of diaquabis[(phenylsulfinyl) acetato[bis(pyridine)copper(II) and bis[(benzylthio) acetato]bis(pyridine)copper(II)
Journal name Polyhedron   Check publisher's open access policy
ISSN 0277-5387
Publication date 1985-01-01
Sub-type Article (original research)
DOI 10.1016/S0277-5387(00)86978-8
Open Access Status Not yet assessed
Volume 4
Issue 8
Start page 1443
End page 1448
Total pages 6
Language eng
Subject 1606 Physical and Theoretical Chemistry
1604 Inorganic Chemistry
2505 Materials Chemistry
Abstract The crystal structures of diaquabis[(phenylsulfinyl) acetato]bis(pyridine)-copper(II), (1), and bis[(benzylthio) acetato]bis(pyridine)copper(II) (2) have been determined using X-ray diffraction. In (1), the copper atom is at the centre of a distorted octahedron with the equatorial sites occupied in a trans configuration by two unidentate (phenylsulfinyl)acetate oxygens [Cu-O, 1.97(2),2.01(2)Å] and two pyridine nitrogens [Cu-N, 1.99(2),2.05(2) Å] with water molecules completing the polyhedron [Cu-O, 2.51(2),2.58(2) Å]. The copper atom in (2) is at the inversion centre of a distorted octahedron having in the equatorial sites, trans-related pyridine nitrogens [Cu-N, 1.993(3) Å] and four oxygens from two asymmetric bidentate (benzylthio)acetate ligands [Cu-O, 2.012(3), 2.510(5) Å].
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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