A new dinuclear amine-cobalt(III) complex containing two bridging amide ions

Angus P.M., Fairlie D.P., Gunasingam R., Zhu T. and Jackson W.G. (1993) A new dinuclear amine-cobalt(III) complex containing two bridging amide ions. Inorganica Chimica Acta, 209 2: 123-127. doi:10.1016/S0020-1693(00)85132-4


Author Angus P.M.
Fairlie D.P.
Gunasingam R.
Zhu T.
Jackson W.G.
Title A new dinuclear amine-cobalt(III) complex containing two bridging amide ions
Journal name Inorganica Chimica Acta   Check publisher's open access policy
ISSN 0020-1693
Publication date 1993-07-01
Year available 1993
Sub-type Article (original research)
DOI 10.1016/S0020-1693(00)85132-4
Open Access Status Not yet assessed
Volume 209
Issue 2
Start page 123
End page 127
Total pages 5
Place of publication LAUSANNE 1
Publisher ELSEVIER SCIENCE SA LAUSANNE
Language eng
Abstract The classic tribridged dimer, [(NH3)3Co(NH2)2(OH)Co(NH3)3]3+, the first tribridged species to contain two bridging NH2- groups, has been characterized. Some derivatives in which the OH- bridge has been replaced by another are also described. H-1 NMR studies in dimethyl sulfoxide reveal bridging NH2- and OH- proton signals at characteristically high chemical shifts, especially bridging OH- which is above SiMe4, but the shifts are quite sensitive to structure.
Keyword Chemistry, Inorganic & Nuclear
Chemistry
CHEMISTRY, INORGANIC & NUCLEAR
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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