Enantioselective total synthesis of (-)-dactylolide

Louis, I, Hungerford, NL, Humphries, EJ and McLeod, MD (2006) Enantioselective total synthesis of (-)-dactylolide. Organic Letters, 8 6: 1117-1120. doi:10.1021/ol053092b

Author Louis, I
Hungerford, NL
Humphries, EJ
McLeod, MD
Title Enantioselective total synthesis of (-)-dactylolide
Journal name Organic Letters   Check publisher's open access policy
ISSN 1523-7060
Publication date 2006-03-16
Year available 2006
Sub-type Article (original research)
DOI 10.1021/ol053092b
Open Access Status Not yet assessed
Volume 8
Issue 6
Start page 1117
End page 1120
Total pages 4
Language eng
Subject 1313 Molecular Medicine
Abstract The enantioselective total synthesis of (-)-dactylolide is reported. The absolute stereochemistry of the tetrahydropyran was established by catalytic asymmetric Jacobsen hetero-Diels-Alder reaction. The remote C19 stereocenter was introduced by a sequence of chelation-controlled Grignard addition and Ireland-Claisen rearrangement.
Keyword Chemistry, Organic
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
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Citation counts: TR Web of Science Citation Count  Cited 44 times in Thomson Reuters Web of Science Article | Citations
Scopus Citation Count Cited 47 times in Scopus Article | Citations
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Created: Fri, 13 Jan 2017, 23:23:58 EST by Natasha Hungerford