Chiral ruthenium(II) complexes as supramolecular building blocks for heterometallic self-assembly

Iranmanesh, Hasti, Arachchige, Kasun S. A., Bhadbhade, Mohan, Donald, William A., Liew, Jane Y., Liu, Kenny T. -C., Luis, Ena T., Moore, Evan G., Price, Jason R., Yan, Hong, Yang, Jiajia and Beves, Jonathon E. (2016) Chiral ruthenium(II) complexes as supramolecular building blocks for heterometallic self-assembly. Inorganic Chemistry, 55 24: 12737-12751. doi:10.1021/acs.inorgchem.6b02007


Author Iranmanesh, Hasti
Arachchige, Kasun S. A.
Bhadbhade, Mohan
Donald, William A.
Liew, Jane Y.
Liu, Kenny T. -C.
Luis, Ena T.
Moore, Evan G.
Price, Jason R.
Yan, Hong
Yang, Jiajia
Beves, Jonathon E.
Title Chiral ruthenium(II) complexes as supramolecular building blocks for heterometallic self-assembly
Journal name Inorganic Chemistry   Check publisher's open access policy
ISSN 1520-510X
0020-1669
Publication date 2016-12-19
Sub-type Article (original research)
DOI 10.1021/acs.inorgchem.6b02007
Open Access Status Not yet assessed
Volume 55
Issue 24
Start page 12737
End page 12751
Total pages 15
Place of publication Washington, DC, United States
Publisher American Chemical Society
Language eng
Subject 1606 Physical and Theoretical Chemistry
1604 Inorganic Chemistry
Abstract A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, which was characterized by single-crystal X-ray crystallography.
Q-Index Code C1
Q-Index Status Provisional Code
Grant ID DP160100870
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: HERDC Pre-Audit
School of Chemistry and Molecular Biosciences
 
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