Reactions of TIN(II) halides with compounds containing a transition metalcarbon σ-bond

Cole B.J., Cotton J.D. and McWilliam D. (1974) Reactions of TIN(II) halides with compounds containing a transition metalcarbon σ-bond. Journal of Organometallic Chemistry, 64 2: 205-221. doi:10.1016/S0022-328X(00)87912-7


Author Cole B.J.
Cotton J.D.
McWilliam D.
Title Reactions of TIN(II) halides with compounds containing a transition metalcarbon σ-bond
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1974-01-08
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)87912-7
Open Access Status
Volume 64
Issue 2
Start page 205
End page 221
Total pages 17
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Tin(II) chloride inserts into the ironcarbon σ-bond in MeFe(CO)2Cp (Cp = cyclopentadienyl), in refluxing methanol or THF, to give MeClSnFe(CO)2- Cp and traces of Cl3SnFe(CO)2Cp, but, with EtFe(CO)2Cp, a mixture of the insertion product, Cl3SnFe(CO)2Cp, and Cl2Sn[Fe(CO)2Cp]2 is formed. Insertion of tin(II) chloride was not observed for MeMo(CO)3Cp and MeMn(CO)5; in these reactions, and in those between tin(II)_bromide and MeFe(CO)2Cp, EtFe(CO)2Cp and Memo(CO)3Cp, mixtures of halo-metal carbonyls and halotin-metal carbonyls result.
Q-Index Code C1
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 13 Sep 2016, 12:19:21 EST by System User