Reaction of hexamethylditin and related species with trimethyltin chloride

Arnold D.P., Cuthbertson M.J. and Wells P.R. (1980) Reaction of hexamethylditin and related species with trimethyltin chloride. Journal of Organometallic Chemistry, 184 1: 39-47. doi:10.1016/S0022-328X(00)94361-4


Author Arnold D.P.
Cuthbertson M.J.
Wells P.R.
Title Reaction of hexamethylditin and related species with trimethyltin chloride
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1980-01-08
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)94361-4
Open Access Status Not yet assessed
Volume 184
Issue 1
Start page 39
End page 47
Total pages 9
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Despite unsuccessful attempts to trap it, evidence is presented that the polymeric "dimethyltin" obtained from hexamethyltin by reaction with trimethyltin chloride arises from monomeric dimethyltin as a reactive intermediate. Polymerisation proceeds either by insertion into SnSn or into SnCl bonds to yield mixtures of products of the type (CH3)2n+2Snn and perhaps (CH3)2nSnn with n ≥ 8 as judged by mass spectrometry.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 30 Aug 2016, 12:51:24 EST by System User