15N NMR spectra of pentaamminerhodium(III) complexes

Appleton T.G., Hall J.R. and Ralph S.F. (1988) 15N NMR spectra of pentaamminerhodium(III) complexes. Inorganic Chemistry, 27 24: 4435-4437.

Author Appleton T.G.
Hall J.R.
Ralph S.F.
Title 15N NMR spectra of pentaamminerhodium(III) complexes
Journal name Inorganic Chemistry   Check publisher's open access policy
ISSN 0020-1669
Publication date 1988-01-01
Sub-type Article (original research)
Open Access Status Not yet assessed
Volume 27
Issue 24
Start page 4435
End page 4437
Total pages 3
Subject 1604 Human Geography
Abstract A series of pentaamminerhodium(III) complexes, Rh(NH3)5Zn+, has been prepared, with 80% enrichment in 15N (Z = H2O, OH-, Cl-, Br-, I-, NH3, -ONO-, -NO2 -, -NCS-, -SCN-, -NCO-, CN-). The 1H-decoupled 15N NMR spectra show two doublets (from coupling to 103Rh) with approximate intensity ratio 4:1. δN and 1J(Rh-N) are sensitive to Z, especially for the unique ammine trans to Z. Good correlations exist between δN in this series and δN in the corresponding cobalt(III) complexes Co(NH3)5Zn+ and platinum(II) complexes Pt(NH3)3Zm+. J(Rh-N) trans to Z also correlates well with J(Pt-N) trans to Z in the platinum series.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 30 Aug 2016, 11:57:38 EST by System User