Reactions of platinum(II) aqua complexes. 2. 195Pt NMR study of reactions between the tetraaquaplatinum(II) cation and chloride, hydroxide, perchlorate, nitrate, sulfate, phosphate, and acetate

Appleton T.G., Hall J.R., Ralph S.F. and Thompson C.S.M. (1984) Reactions of platinum(II) aqua complexes. 2. 195Pt NMR study of reactions between the tetraaquaplatinum(II) cation and chloride, hydroxide, perchlorate, nitrate, sulfate, phosphate, and acetate. Inorganic Chemistry, 23 22: 3521-3525. doi:10.1021/ic00190a017


Author Appleton T.G.
Hall J.R.
Ralph S.F.
Thompson C.S.M.
Title Reactions of platinum(II) aqua complexes. 2. 195Pt NMR study of reactions between the tetraaquaplatinum(II) cation and chloride, hydroxide, perchlorate, nitrate, sulfate, phosphate, and acetate
Journal name Inorganic Chemistry   Check publisher's open access policy
ISSN 0020-1669
Publication date 1984-01-01
Sub-type Article (original research)
DOI 10.1021/ic00190a017
Volume 23
Issue 22
Start page 3521
End page 3525
Total pages 5
Subject 1604 Human Geography
Abstract Complexes formed in solution between Pt(H2O)4 2+ (I) and anionic ligands Am-, Pt(A)n(H2O)4-n (2-mn)+, have been characterized by 195Pt NMR spectra (Am- = Cl- (n = 1-4), ONO2 - (n = 1-3), OSO3 2- (n = 1, 2), OPO3H2 - (n = 1-4), and O2CCH3 - (n = 1)). No distinct perchlorato complexes were observed. An alkaline solution gave a single resonance assigned to Pt(OH)4 2-. Concentrated solutions disproportionated to Pt and Pt(OH)6 2-. Peroxide oxidation of acid and alkaline solutions gave respectively "PtO2·3H2O" and Pt(OH)6 2-.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
Versions
Version Filter Type
Citation counts: Scopus Citation Count Cited 100 times in Scopus Article | Citations
Google Scholar Search Google Scholar
Created: Tue, 23 Aug 2016, 11:31:21 EST by System User