Electrophilic cleavage of 1-allyl-1,2,5-trimethyl-1-silacyclopentane. Stereochemistry at silicon

Franke F., Cuthbertson M.J. and Wells P.R. (1984) Electrophilic cleavage of 1-allyl-1,2,5-trimethyl-1-silacyclopentane. Stereochemistry at silicon. Journal of Organic Chemistry, 49 7: 1258-1261. doi:10.1021/jo00181a024


Author Franke F.
Cuthbertson M.J.
Wells P.R.
Title Electrophilic cleavage of 1-allyl-1,2,5-trimethyl-1-silacyclopentane. Stereochemistry at silicon
Journal name Journal of Organic Chemistry   Check publisher's open access policy
ISSN 0022-3263
Publication date 1984-01-01
Sub-type Article (original research)
DOI 10.1021/jo00181a024
Open Access Status
Volume 49
Issue 7
Start page 1258
End page 1261
Total pages 4
Subject 1605 Policy and Administration
Abstract The preparation of mixtures of the isomers of 1-allyl-1,2,5-trimethyl-1-silacyclopentane and some of their reactions with electrophiles are described. Individual isomers and reaction products have not been isolated but have been characterized by 1H and 13C NMR spectroscopy. Cleavage of the allyl group may proceed with retention, inversion, or loss of configuration at silicon according to the reagent employed.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 16 Aug 2016, 14:27:41 EST by System User