Dimethylplatinum(IV) compounds. V. Preparation and reations of bis(salicylaldehydato) complexes

Hall J.R. and Swile G.A. (1978) Dimethylplatinum(IV) compounds. V. Preparation and reations of bis(salicylaldehydato) complexes. Journal of Organometallic Chemistry, 161 1: 121-138. doi:10.1016/S0022-328X(00)80917-1


Author Hall J.R.
Swile G.A.
Title Dimethylplatinum(IV) compounds. V. Preparation and reations of bis(salicylaldehydato) complexes
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1978-11-14
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)80917-1
Volume 161
Issue 1
Start page 121
End page 138
Total pages 18
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Two geometrical isomers of Pt(CH3)2(Sal)2 have been prepared and identified by 1H NMR spectra. Some reactions of isomer A (phenolic oxygen atoms trans to CH3) and isomer B (aldehydic oxygen atoms trans to CH3) are reported. Isomer B reacts with C5D5N to produce species containing unidentate Sal in solution, while isomer A tends to lose Sal with formation of hydroxo species. Primary amines react with isomer B to form salicylaldimine complexes. Isomer A reacts with en to form Pt(CH3)2en(0H)2.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 16 Aug 2016, 13:51:02 EST by System User