ortho-Effects on carbon monoxide insertion in benzyl-molybdenum complexes

Cotton J.D., Kimlin H.A. and Markwell R.D. (1982) ortho-Effects on carbon monoxide insertion in benzyl-molybdenum complexes. Journal of Organometallic Chemistry, 232 4: . doi:10.1016/S0022-328X(00)89219-0


Author Cotton J.D.
Kimlin H.A.
Markwell R.D.
Title ortho-Effects on carbon monoxide insertion in benzyl-molybdenum complexes
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1982-07-06
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)89219-0
Volume 232
Issue 4
Total pages 1
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract The formation of phosphine-substituted acylmolybdenums [(η5-C5H5)-(CO)2(PPh3)Mo(COR)], from reactions between substituted benzylmolybdenum complexes and triphenylphosphine in acetonitrile, is enhanced by the presence of a single bulky substituent in the ortho-position. However di-substitution (for i-Pr, Cl and OMe) causes a pronounced lowering of reactivity. The results are interpreted in terms of the steric demands of the reaction.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 16 Aug 2016, 13:02:33 EST by System User