Ion-Ion-Solvent Interactions in Solution. X Group 2 Perchlorates in Water

James D.W. and Cutler P.G. (1985) Ion-Ion-Solvent Interactions in Solution. X Group 2 Perchlorates in Water. Australian Journal of Chemistry, 39 1: 137-147. doi:10.1071/CH9860137


Author James D.W.
Cutler P.G.
Title Ion-Ion-Solvent Interactions in Solution. X Group 2 Perchlorates in Water
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1985-01-01
Sub-type Article (original research)
DOI 10.1071/CH9860137
Open Access Status Not yet assessed
Volume 39
Issue 1
Start page 137
End page 147
Total pages 11
Subject 1600 Chemistry
Abstract Solutions of Mg(ClO4)2, Ca(ClO4)2 and Sr(ClO4)2 have been studied at a variety of concentrations up to saturation by means of infrared absorption, Raman scattering and multinuclear n.m.r. spectroscopy. For solutions of Mg(ClO4)2 there was little ion association up to saturation but for the other two salts association to both solvent shared anion-cation complexes and contact anion-cation complexes was identified. The nature of the association process was probed by using line broadening for the quadrupolar nuclei 17O, 35Cl and 43Ca. The extent of association to solvent shared anion-cation complexes was found to increase in the series Mg2+ < Ca2+ < Sr2+.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 12 Jul 2016, 13:40:17 EST by System User