Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands

Appleton T.G., Hall J.R., Neale D.W. and Williams M.A. (1984) Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands. Journal of Organometallic Chemistry, 276 3: . doi:10.1016/0022-328X(84)80669-5

Author Appleton T.G.
Hall J.R.
Neale D.W.
Williams M.A.
Title Displacement of norbornadiene (NBD) from PtR2(NBD) (R = Me, CF3) by weak ligands
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1984-11-27
Sub-type Article (original research)
DOI 10.1016/0022-328X(84)80669-5
Open Access Status Not yet assessed
Volume 276
Issue 3
Total pages 1
Language eng
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Norbornadiene (NBD) is more easily displaced from PtMe2 (NBD) by other ligands than is cyclooctadiene (COD) from PtMe2 (COD). cis-PtMe2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO) have been prepared in this way. cis-PtMe2py2 is very reactive toward oxidative addition. Pyridine can usually be removed from the platinum(IV) products using acid. NBD is even more readily displaced from Pt(CF3)2 (NBD), giving cis-Pt(CF3)2L2 (L = py, 1 2tmen, 1 2en, NH3, DMSO, NCR, DMF, CN-, I-, acac-). cis-Pt(CF3)2py2 with CF2I gives fac-Pt(CF3)3py2I.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
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