Deprotonation of metal complexes derived from ligands containing pyrrole, pyrazole and indene residues

Chiswell B. (1972) Deprotonation of metal complexes derived from ligands containing pyrrole, pyrazole and indene residues. Inorganica Chimica Acta, 6 C: 629-634. doi:10.1016/S0020-1693(00)91870-X


Author Chiswell B.
Title Deprotonation of metal complexes derived from ligands containing pyrrole, pyrazole and indene residues
Journal name Inorganica Chimica Acta   Check publisher's open access policy
ISSN 0020-1693
Publication date 1972-01-01
Sub-type Article (original research)
DOI 10.1016/S0020-1693(00)91870-X
Volume 6
Issue C
Start page 629
End page 634
Total pages 6
Subject 1303 Specialist Studies in Education
1604 Human Geography
1606 Political Science
2505 Materials Chemistry
Abstract The synthesis of several new planar nitrogenous tridentate ligands, specially designed to present their donor atoms at positions very close to the normal octahedral sites of a metal atom, are described. Each of these ligand moieties, when complexed to a metal atom, also possess the potential ability to lose a proton from the periphery of the ligand molecue to yield deprotonated non-charged metal complexes. The lack of change in colour and magnetic moment of complexes of these ligands, upon undergoing such deprotonation reactions, is compared with the marked increase in colour intensity and decrease in magnetic moment when charged complexes containing a 2-pyridylhydrazine entity in the ligand residue undergo similar deprotonation reactions.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 12 Jul 2016, 12:46:56 EST by System User