Reactions of carbodi-imides with palladium(II) compounds

Bycroft B.M. and Cotton J.D. (1973) Reactions of carbodi-imides with palladium(II) compounds. Journal of the Chemical Society, Dalton Transactions, 18: 1867-1870. doi:10.1039/DT9730001867


Author Bycroft B.M.
Cotton J.D.
Title Reactions of carbodi-imides with palladium(II) compounds
Journal name Journal of the Chemical Society, Dalton Transactions
ISSN 1472-7773
Publication date 1973-01-01
Sub-type Article (original research)
DOI 10.1039/DT9730001867
Open Access Status Not yet assessed
Issue 18
Start page 1867
End page 1870
Total pages 4
Language eng
Subject 1600 Chemistry
Abstract New dihalogenobis(carbodi-imide)palladium(II) compounds are formed in the reactions between di-t-butyl- and methyl-t-butylcarbodi-imides and (PhCN)PdX (X = Cl and Br) in dichloromethane solution. In methanol solution, 1,2-addition of solvent to di-o-tolyl-, dicyclohexyl- and methyl-t-butylcarbodi-imides is promoted by Pd, and dihalogenobis(isourea) complexes are obtained. Structures of the compounds are discussed on the basis of i.r. and H n.m.r. observations.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 12 Jul 2016, 10:50:48 EST by System User