Controlling Au photodeposition on large ZnO nanoparticles

Fernando, Joseph F. S., Shortell, Matthew P., Noble, Christopher J., Harmer, Jeffrey R., Jaatinen, Esa A. and Waclawik, Eric R. (2016) Controlling Au photodeposition on large ZnO nanoparticles. ACS Applied Materials and Interfaces, 8 22: 14271-14283. doi:10.1021/acsami.6b03128

Author Fernando, Joseph F. S.
Shortell, Matthew P.
Noble, Christopher J.
Harmer, Jeffrey R.
Jaatinen, Esa A.
Waclawik, Eric R.
Title Controlling Au photodeposition on large ZnO nanoparticles
Journal name ACS Applied Materials and Interfaces   Check publisher's open access policy
ISSN 1944-8252
Publication date 2016-06-08
Year available 2016
Sub-type Article (original research)
DOI 10.1021/acsami.6b03128
Volume 8
Issue 22
Start page 14271
End page 14283
Total pages 13
Place of publication Washington, DC, United States
Publisher American Chemical Society
Language eng
Formatted abstract
This study investigated how to control the rate of photoreduction of metastable AuCl2- at the solid-solution interface of large ZnO nanoparticles (NPs) (50-100 nm size). Band-gap photoexcitation of electronic charge in ZnO by 370 nm UV light yielded Au NP deposition and the formation of ZnO-Au NP hybrids. Au NP growth was observed to be nonepitaxial, and the patterns of Au photodeposition onto ZnO NPs observed by high-resolution transmission electron microscopy were consistent with reduction of AuCl2at ZnO facet edges and corner sites. Au NP photodeposition was effective in the presence of labile oleylamine ligands attached to the ZnO surface; however, when a strong-binding dodecanethiol ligand coated the surface, photodeposition was quenched. Rates of interfacial electron transfer at the ZnO-solution interface were adjusted by changing the solvent, and these rates were observed to strongly depend on the solvent's permittivity (ϵ) and viscosity. From measurements of electron transfer from ZnO to the organic dye toluidine blue at the ZnO-solution interface, it was confirmed that low ϵ solvent mixtures (ϵ ≈ 9.5) possessed markedly higher rates of photocatalytic interfacial electron transfer (∼3.2 × 104 electrons·particle-1·s-1) compared to solvent mixtures with high ϵ (ϵ = 29.9, ∼1.9 × 104 electrons·particle-1·s-1). Dissolved oxygen content in the solvent and the exposure time of ZnO to band-gap, near-UV photoexcitation were also identified as factors that strongly affected Au photodeposition behavior. Production of Au clusters was favored under conditions that caused electron accumulation in the ZnO-Au NP hybrid. Under conditions where electron discharge was rapid (such as in low ϵ solvents), AuCl2- precursor ions photoreduced at ZnO surfaces in less than 5 s, leading to deposition of several small, isolated ∼6 nm Au NP on the ZnO host instead.
Keyword Au
Au-ZnO nanoparticle hybrids
Interfacial electron transfer
Nanoparticle composites
Photochemical reduction
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
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