Amino acid complexes of platinum(IV). I. Trimethylplatinum(IV) complexes with glycinate, iminodiacetate, n-methyliminodiacetate, nitrilotriacetate, and ethylenediamine-tetraacetate

Appleton T.G., Hall J.R. and Lambert L. (1978) Amino acid complexes of platinum(IV). I. Trimethylplatinum(IV) complexes with glycinate, iminodiacetate, n-methyliminodiacetate, nitrilotriacetate, and ethylenediamine-tetraacetate. Inorganica Chimica Acta, 29 C: 89-99. doi:10.1016/S0020-1693(00)89632-2


Author Appleton T.G.
Hall J.R.
Lambert L.
Title Amino acid complexes of platinum(IV). I. Trimethylplatinum(IV) complexes with glycinate, iminodiacetate, n-methyliminodiacetate, nitrilotriacetate, and ethylenediamine-tetraacetate
Journal name Inorganica Chimica Acta   Check publisher's open access policy
ISSN 0020-1693
Publication date 1978-01-01
Sub-type Article (original research)
DOI 10.1016/S0020-1693(00)89632-2
Volume 29
Issue C
Start page 89
End page 99
Total pages 11
Subject 1303 Specialist Studies in Education
1604 Human Geography
1606 Political Science
2505 Materials Chemistry
Abstract Reaction between PtMe3(H2O)+ 3 and sodium glycinate gives a series of glycinato complexes, PtMe3(gly)(H2O), [PtMe3(gly)]2, PtMe3(gly)- 2 and PtMe3(gly)2- 3. Variable-temperature PMR has been used to study rapid intramolecular exchange reactions in PtMe3(gly)(D2O) and PtMe3(gly)- 2 in D2O.Iminodiacetate, N-Methyliminodiacetate, and nitrilotriacetate act as tridentate ligands, coordinating through the N- and two O-atoms. The most stable EDTA complex is (Me3Pt)2(EDTA)2-, in which each Pt-atom is coordinated to one N and two O-atoms of bridging EDTA.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sat, 09 Jul 2016, 16:54:57 EST by System User