Borates and Phosphates of Hexahydromuellitol and Isomuellitol

Fazldeen H. (1982) Borates and Phosphates of Hexahydromuellitol and Isomuellitol. Australian Journal of Chemistry, 35 12: 2589-2592. doi:10.1071/CH9822589


Author Fazldeen H.
Title Borates and Phosphates of Hexahydromuellitol and Isomuellitol
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1982-01-01
Sub-type Article (original research)
DOI 10.1071/CH9822589
Volume 35
Issue 12
Start page 2589
End page 2592
Total pages 4
Subject 1600 Chemistry
Abstract Hexahydromuellitol and isomuellitol are derivatives of a natural product (muellitol), and contain hydroxy groups in their structures which should allow for the formation of ‘cage’ compounds. They were each dissolved in a standard borate solution, and the pH values were measured to determine if complexes of the tridentate type were formed. Hexahydromuellitol caused the pH value of the solution to be depressed considerably, but isomuellitol had no significant effect. Plots of the change in pH value against time showed that a tridentate borate of hexahydromuellitol was formed but not of isomuellitol. Orthophosphates were prepared from both compounds to verify the assigned conformations. The mono- and the di-orthophosphates of hexahydromuellitol were obtained, as was the orthophosphate of isomuellitol.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sat, 09 Jul 2016, 16:54:39 EST by System User