Synthesis infrared raman and PMR spectra of the tetramer: Tetrakis(trimethylthiomethoxyplatinum(IV)), [Pt(CH3)3SCH3]4

Hall J.R., Hirons D.A. and Swile G.A. (1979) Synthesis infrared raman and PMR spectra of the tetramer: Tetrakis(trimethylthiomethoxyplatinum(IV)), [Pt(CH3)3SCH3]4. Journal of Organometallic Chemistry, 174 3: 355-358. doi:10.1016/S0022-328X(00)85600-4


Author Hall J.R.
Hirons D.A.
Swile G.A.
Title Synthesis infrared raman and PMR spectra of the tetramer: Tetrakis(trimethylthiomethoxyplatinum(IV)), [Pt(CH3)3SCH3]4
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1979-08-07
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)85600-4
Volume 174
Issue 3
Start page 355
End page 358
Total pages 4
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Trimethylthiomethoxyplatinum(IV), Pt(CH3)3SCH3, has been prepared and characterised. It is tetrameric in CHCl3 solution and in the vapour state. Infrared and Raman spectra of the solid state have been recorded and also the Raman spectrum of a chloroform solution. Polarized lines at 126, 563, 729, 1255 and 2923 cm-1 are assigned to the totally symmetric modes ν(PtS), ν(PtC), ν(CS), δ(CH3) and ν(CH), respectively. The PMR spectrum in CHCl3 has been recorded, 2J(195PtC1H) 69.7 Hz. The thiomethyl proton signal consists of a septet, 3J(195PtSC1H) 15.5 Hz, which is expected for a tetramer based on interlocking tetrahedra of four Pt(CH3)3 and four SCH3 groups.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sat, 09 Jul 2016, 16:12:34 EST by System User