New bis- and tetrakis-complexes of trimethyl- and dimethyltin(IV) cations: Me3SnL2BPh4 and Me2SnL4(BPh4)2

Kitching W., Das V.G.K. and Moore C.J. (1970) New bis- and tetrakis-complexes of trimethyl- and dimethyltin(IV) cations: Me3SnL2BPh4 and Me2SnL4(BPh4)2. Journal of Organometallic Chemistry, 22 2: 399-402. doi:10.1016/S0022-328X(00)86059-3


Author Kitching W.
Das V.G.K.
Moore C.J.
Title New bis- and tetrakis-complexes of trimethyl- and dimethyltin(IV) cations: Me3SnL2BPh4 and Me2SnL4(BPh4)2
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1970-01-01
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)86059-3
Volume 22
Issue 2
Start page 399
End page 402
Total pages 4
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract New examples of complexes of types Me2SnL4(BPh4)2 and Me3SnL2BPh4 are reported where L = Ph3PO, Ph3AsO and (p-CH3C6H4)3AsO. Consideration of proton magnetic resonance data confirms that, in solution, phenyl group transfer from boron to tin occurs so that Me2SnPh2 and Me3SnC6H5 may be formed, thus accounting for some puzzling features in previous spectra of complexes of these types. Some vibrational spectral data are also presented and shown to be consistent with molecular structures previously suggested.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sat, 09 Jul 2016, 15:41:15 EST by System User