The stereochemistry of organomercury compounds. II. A redetermination of the structure of mercury(II) cyanide by neutron diffraction

Seccombe R.C. and Kennard C.H.L. (1969) The stereochemistry of organomercury compounds. II. A redetermination of the structure of mercury(II) cyanide by neutron diffraction. Journal of Organometallic Chemistry, 18 2: 243-247.

Author Seccombe R.C.
Kennard C.H.L.
Title The stereochemistry of organomercury compounds. II. A redetermination of the structure of mercury(II) cyanide by neutron diffraction
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1969-01-01
Sub-type Article (original research)
Volume 18
Issue 2
Start page 243
End page 247
Total pages 5
Subject 2505 Materials Chemistry
2501 Materials Science (miscellaneous)
1606 Political Science
1605 Policy and Administration
1604 Human Geography
1501 Accounting, Auditing and Accountability
1303 Specialist Studies in Education
Abstract The crystal structure of mercury(II) cyanide, Hg(CN)2, has been determined using three dimensional neutron diffraction data. The compound crystallizes out in a tetragonal unit cell, space group I42d; cell dimensions, a = 9.643, c = 8.88 ». There are eight molecules per unit cell. Interatomic distances and angles are: Hg-C, 2.015(3); C-N, 1.137(3); non bonding Hg-N, 2.742(3) »; C-Hg-C, 175.0(2)°; Hg-C-N, 177.0(3)°.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
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Created: Sat, 09 Jul 2016, 15:32:20 EST by System User