Displacement of norbornadiene (NBD) from the mixed alkyl compound, Pt(CH3) (CF3)(NBD) by various ligands and the insertion of difluorocarbene into a PtCH3 bond promoted by the addition of iodide ion to Pt(CH3) (CF3)(NBD)

Appleton T.G., Hall J.R., Mathieson M.T. and Neale D.W. (1993) Displacement of norbornadiene (NBD) from the mixed alkyl compound, Pt(CH3) (CF3)(NBD) by various ligands and the insertion of difluorocarbene into a PtCH3 bond promoted by the addition of iodide ion to Pt(CH3) (CF3)(NBD). Journal of Organometallic Chemistry, 453 2: 307-316. doi:10.1016/0022-328X(93)83128-I


Author Appleton T.G.
Hall J.R.
Mathieson M.T.
Neale D.W.
Title Displacement of norbornadiene (NBD) from the mixed alkyl compound, Pt(CH3) (CF3)(NBD) by various ligands and the insertion of difluorocarbene into a PtCH3 bond promoted by the addition of iodide ion to Pt(CH3) (CF3)(NBD)
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1993-07-13
Sub-type Article (original research)
DOI 10.1016/0022-328X(93)83128-I
Volume 453
Issue 2
Start page 307
End page 316
Total pages 10
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Pt(CH3)(CF3)(NBD) was found to react with neutral ligands L to give cis-Pt(CH3)(CF3)L2 (L2 = 1,2-bis(diphenylphosphino)ethane (dppe); 2,2′-dipyridyl (bipy); N,N,N′,N′-tetramethylethylenediamine (tmen); and L = pyridine (py); dimethylsulfoxide-S (DMSO). These reactions occurred less readily than with Pt(CF3)2(NBD). With (CH3CN, cis-Pt(CH3(CF3)(NBD) gave cis-Pt(CH3)-(CF3)(CH3CN)2 in equilibrium with starting materials. N,N-dimethylformamide (DMF) did not react. Pt(CH3)(CF3)(NBD)reacted with iodide to give a mixture of Pt(CH3)I(NBD), Pt(CF3)I(NBD), and Pt(-CF2CH3)I(NBD), the product of a formal insertion of a difluorocarbene moiety into a PtCH3 bond. The products were characterized by multinuclear NMR spectroscopy then converted into dppe derivatives, which were separated and isolated.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import
 
Versions
Version Filter Type
Citation counts: Scopus Citation Count Cited 9 times in Scopus Article | Citations
Google Scholar Search Google Scholar
Created: Tue, 05 Jul 2016, 15:14:03 EST by System User