Derivatives of bicyclo [2, 2, 2] octane-2, 6:3, 5-dicarbolactone

Carman R.M. and Smith S.S. (1981) Derivatives of bicyclo [2, 2, 2] octane-2, 6:3, 5-dicarbolactone. Australian Journal of Chemistry, 34 6: 1285-1294. doi:10.1071/CH9811285


Author Carman R.M.
Smith S.S.
Title Derivatives of bicyclo [2, 2, 2] octane-2, 6:3, 5-dicarbolactone
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1981-01-01
Sub-type Article (original research)
DOI 10.1071/CH9811285
Volume 34
Issue 6
Start page 1285
End page 1294
Total pages 10
Subject 1600 Chemistry
Abstract The reactions of the title dilactone with both acid and base are discussed. Evidence is presented for stable γ-lactones in the bicyclo[2, 2, 2]octane-2, 6-carbolactone series. Epimerization α to hindered acid groups occurs under acetylating conditions to relieve steric strain in this system.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 05 Jul 2016, 12:55:32 EST by System User