The reaction of propene with iodine bromide

Alberts V. and Carman R.M. (1980) The reaction of propene with iodine bromide. Australian Journal of Chemistry, 33 2: 455-459. doi:10.1071/CH9800455

Author Alberts V.
Carman R.M.
Title The reaction of propene with iodine bromide
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1980-01-01
Sub-type Article (original research)
DOI 10.1071/CH9800455
Volume 33
Issue 2
Start page 455
End page 459
Total pages 5
Subject 1600 Chemistry
Abstract Iodobromination of propene gives a mixture (c. 60: 40) of 2-bromo-1-iodopropane and 1-bromo- 2-iodopropane. This mixture of kinetic control converts into an equilibrium (c. 70: 30) mixture with heat. The addition to the double bond is postulated to occur through a bridged iodonium ion rather than through a simple carbocation, and hence Markownikoff’s rule need not apply to this system.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
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