(PeniaaikyJditln)IKhiums: In (Trfaikyliin)Iiihium Preparations

Khchtag W., Clazowy H.A. and Drew G.M. (1982) (PeniaaikyJditln)IKhiums: In (Trfaikyliin)Iiihium Preparations. Organometallics, 1 9: 1244-1246.

Author Khchtag W.
Clazowy H.A.
Drew G.M.
Title (PeniaaikyJditln)IKhiums: In (Trfaikyliin)Iiihium Preparations
Journal name Organometallics   Check publisher's open access policy
ISSN 0276-7333
Publication date 1982-01-01
Sub-type Article (original research)
Open Access Status Not yet assessed
Volume 1
Issue 9
Start page 1244
End page 1246
Total pages 3
Subject 1604 Human Geography
1605 Policy and Administration
Abstract (Pentaalkyliditin)lithiums are demonstrated to be present in preparations of (triaikyltin)lithium reagents (from the triaikyltin haiide and lithium In tetrahydrofuran) by direct observation (119Sn NMR) and alkylation to R5Sn2R' (R = methyl, propyl, isopropyi; R' = eycfohexyl, methyl}. Gyclohexyiation of {/-C3H7)5Sn2li proceeds by a free radical route. The R6Sa2iJ species are considered to arise by oxidative addition of R3SnLi to R28rt, formed by R3SnlR2Sn:RLi, dissociation of which is promoted by R6Sn2 scavenging of RLi.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
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Created: Tue, 28 Jun 2016, 15:31:38 EST by System User