Oxidation of isomuellitol and hexahydromuellitol with chromium trioxide

Fazldeen H. (1987) Oxidation of isomuellitol and hexahydromuellitol with chromium trioxide. Australian Journal of Chemistry, 40 5: 999-1002. doi:10.1071/CH9870999


Author Fazldeen H.
Title Oxidation of isomuellitol and hexahydromuellitol with chromium trioxide
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1987-01-01
Sub-type Article (original research)
DOI 10.1071/CH9870999
Open Access Status Not yet assessed
Volume 40
Issue 5
Start page 999
End page 1002
Total pages 4
Subject 1600 Chemistry
Abstract Chromate oxidation of isomuellitol (2) led cleanly to the production of a cyclic trione, 2, 2, 9, 9, 15, 15-hexamethyl-l, 8, 14-trioxatrispiro[4.1.4.1.4.1]octadecane-6, 12, 18-trione (4), but the product derived from hexahydromuellitol (3) was an unexpected γ-lactone, 4-hydroxy-2, 4-bis(3′- methylbutyl)-3-(4 ″-methyl-l″-oxopentyloxy)-5-oxotetrahydrofuran-2-carboxylic acid (5).
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 28 Jun 2016, 14:02:05 EST by System User