Carbon monoxide insertion reactions in substituted cyclopentadienylmolybdenum complexes

Cotton J.D. and Kimlin H.A. (1985) Carbon monoxide insertion reactions in substituted cyclopentadienylmolybdenum complexes. Journal of Organometallic Chemistry, 294 2: 213-217. doi:10.1016/0022-328X(85)87471-4


Author Cotton J.D.
Kimlin H.A.
Title Carbon monoxide insertion reactions in substituted cyclopentadienylmolybdenum complexes
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1985-10-15
Sub-type Article (original research)
DOI 10.1016/0022-328X(85)87471-4
Open Access Status Not yet assessed
Volume 294
Issue 2
Start page 213
End page 217
Total pages 5
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract The reactions of [(η5-C5Me5)(CO)3MoCH2Ph] and [(η5-C5H4Me)(CO)3MoCH2-Ph] with tertiary phosphines and alkyl isocyanides in polar solvents to yield phosphine-substituted molybdenum acyl complexes have been explored and compared with the behaviour of the unsubstituted cyclopentadienyl compound. For the pentamethylcyclopentadienyl complex, reaction is restricted to tertiary phosphines with small cone angles. Unlike the cyclopentadienyl system, a mixture of cis- and trans-acyl products is formed.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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