Preparation of dimethylplatinum(IV) and monomethylplatinum(IV) compounds from monomethylplatinum(II) compounds

Hall J.R. and Swile G.A. (1974) Preparation of dimethylplatinum(IV) and monomethylplatinum(IV) compounds from monomethylplatinum(II) compounds. Journal of Organometallic Chemistry, 76 2: 257-263. doi:10.1016/S0022-328X(00)84637-9


Author Hall J.R.
Swile G.A.
Title Preparation of dimethylplatinum(IV) and monomethylplatinum(IV) compounds from monomethylplatinum(II) compounds
Journal name Journal of Organometallic Chemistry   Check publisher's open access policy
ISSN 0022-328X
Publication date 1974-08-20
Sub-type Article (original research)
DOI 10.1016/S0022-328X(00)84637-9
Open Access Status
Volume 76
Issue 2
Start page 257
End page 263
Total pages 7
Subject 1303 Specialist Studies in Education
1501 Accounting, Auditing and Accountability
1604 Human Geography
1605 Policy and Administration
1606 Political Science
2501 Materials Science (miscellaneous)
2505 Materials Chemistry
Abstract Using PtCH3(NBD)I (NBD = norbornadiene) as starting material, compounds of the type PtCH3L2I (L2 = 1,5-cyclooctadiene and N,N,N′,N′-tetramethylethylenediamine, L = 3,5-lutidine and benzylamine) have been prepared and characterized by 1H NMR and elemental analysis. The compounds with L = lutidine, L2 = N,N,N′,N′-tetramethylethylenediamine undergo oxidative addition with both CH3I and I2 to yield dimethylplatinum (IV) and monomethylplatinum(IV) compounds respectively.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 28 Jun 2016, 10:36:03 EST by System User