Electrophilic substitution with allylic rearrangement (SE′). syn or anti stereoselectivity in trifluoroacetolysis of 4-alkylcyclohex-2-enylsilanes, -germanes and -stannanes

Young D., Kitching W. and Wickham G. (1983) Electrophilic substitution with allylic rearrangement (SE′). syn or anti stereoselectivity in trifluoroacetolysis of 4-alkylcyclohex-2-enylsilanes, -germanes and -stannanes. Tetrahedron Letters, 24 51: 5789-5792. doi:10.1016/S0040-4039(00)94202-3


Author Young D.
Kitching W.
Wickham G.
Title Electrophilic substitution with allylic rearrangement (SE′). syn or anti stereoselectivity in trifluoroacetolysis of 4-alkylcyclohex-2-enylsilanes, -germanes and -stannanes
Journal name Tetrahedron Letters   Check publisher's open access policy
ISSN 0040-4039
Publication date 1983-01-01
Sub-type Article (original research)
DOI 10.1016/S0040-4039(00)94202-3
Volume 24
Issue 51
Start page 5789
End page 5792
Total pages 4
Subject 1303 Specialist Studies in Education
1605 Policy and Administration
3002 Drug Discovery
Abstract Cis-4-alkylcyclohex-2-enyl derivatives of silicon, germanium and tin, with quasiaxial metallo groups, experience stereospecific γ-anti trifluoroacetolysis (to yield 4-alkylcyclohexene), whereas the corresponding trans-isomers show less specificity.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 14 Jun 2016, 13:30:34 EST by System User