The multidentate chemistry of Manganese(II).I. Hybrid tridentate ligand complexes

Chiswell B. and Lee K.W. (1972) The multidentate chemistry of Manganese(II).I. Hybrid tridentate ligand complexes. Inorganica Chimica Acta, 6 C: 567-570. doi:10.1016/S0020-1693(00)91858-9


Author Chiswell B.
Lee K.W.
Title The multidentate chemistry of Manganese(II).I. Hybrid tridentate ligand complexes
Journal name Inorganica Chimica Acta   Check publisher's open access policy
ISSN 0020-1693
Publication date 1972-01-01
Sub-type Article (original research)
DOI 10.1016/S0020-1693(00)91858-9
Volume 6
Issue C
Start page 567
End page 570
Total pages 4
Subject 1303 Specialist Studies in Education
1604 Human Geography
1606 Political Science
2505 Materials Chemistry
Abstract The complex compounds obtained from the interaction of manganese(II) salts and four new tridentate ligands, each possessing the donor set NNAs, and prepared by the Schiff-base condensation of σ-dimethyl or σ-diethylarsinoaniline, are described. Three types of complex were obtained: (i) [Mn ligand X2] (where X = Cl. Br, or I); ii, [Mn(ligand)2]Y2 (where Y = ClO4 or BPh4); (iii) Mn Ligand (NCS)2. Physical measurements have been used to demonstrate that in each case the ligands act as tridentates, and that type (i) complexes are five-coordinate, type (ii) complexes are octahedral, and type (iii) complexes are polymeric octahedral species. Attempts to obtain manganese(II) complexes of various other ligands with the donor sets NNAs and ONAs were unsuccessful.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 14 Jun 2016, 11:53:20 EST by System User