Alkaloids of the Australian Rutaceae: Acronychia baueri. III.The Structure of Acronycine

Drummond L.J. and Lahey F.N. (1949) Alkaloids of the Australian Rutaceae: Acronychia baueri. III.The Structure of Acronycine. Australian Journal of Chemistry, 2 4: 630-638. doi:10.1071/CH9490630


Author Drummond L.J.
Lahey F.N.
Title Alkaloids of the Australian Rutaceae: Acronychia baueri. III.The Structure of Acronycine
Journal name Australian Journal of Chemistry   Check publisher's open access policy
ISSN 1445-0038
Publication date 1949-01-01
Sub-type Article (original research)
DOI 10.1071/CH9490630
Open Access Status Not Open Access
Volume 2
Issue 4
Start page 630
End page 638
Total pages 9
Subject 1600 Chemistry
Abstract Oxidative degradations of acronycine with nitric acid and ozone have been studied. Hot concentrated nitric acid converts noracronycine and nordihydroacronycine into l-methyl-4-quinolone-3-carboxylic acid while nitric acid on acronycine under the same conditions yields first trinitroacronycine and finally 6.nitro-l-methyl-4-quinolone- 3-carboxylic acid. Ozonolysis of acronycine gives a phenolic aldehyde, C16H13O4N, which has been deduced to be 1- or 3-formyl-2-hydroxy-4-methoxy-10-methylacridone (V or VII). These data together with information supplied in Part II indicate acronycine to be either 4-methoxy-2′, 2′, l0-trimethyl-α-pyrano-(5′, 6′-1, 2)acrid-5-one (IV) or 4-methoxy-2′, 2′, 10-trimethyl-α-pyrano.(5′, 6′-3, 2)acrid-5-one (VI).
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collection: Scopus Import - Archived
 
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Created: Tue, 14 Jun 2016, 11:51:53 EST by System User