Thermodynamic reevaluation of the Fe-O system

Hidayat, Taufiq, Shishin, Denis, Jak, Evgueni and Decterov, Sergei A. (2015) Thermodynamic reevaluation of the Fe-O system. CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry, 48 131-144. doi:10.1016/j.calphad.2014.12.005

Author Hidayat, Taufiq
Shishin, Denis
Jak, Evgueni
Decterov, Sergei A.
Title Thermodynamic reevaluation of the Fe-O system
Journal name CALPHAD: Computer Coupling of Phase Diagrams and Thermochemistry   Check publisher's open access policy
ISSN 0364-5916
Publication date 2015-03-01
Year available 2014
Sub-type Article (original research)
DOI 10.1016/j.calphad.2014.12.005
Open Access Status Not Open Access
Volume 48
Start page 131
End page 144
Total pages 14
Place of publication Kidlington, Oxford, United Kingdom
Publisher Pergamon Press
Language eng
Formatted abstract
The Fe–O system has been assessed over the whole composition range to produce a self-consistent set of thermodynamic properties of all condensed phases from 25 °C to above the liquidus temperatures at ambient pressure. The liquid phase from metallic liquid to oxide melt is described by a single model developed within the framework of the Quasichemical Formalism. The model reflects the existence of strong short-range ordering in oxide liquid at approximately FeO and Fe2O3 compositions. Parameters of thermodynamic models have been optimized to reproduce all available thermodynamic and phase equilibrium data. In particular, the heat capacity and entropy of wüstite is described better than in the previous assessments.
Keyword Fe-O system
Critical assessment
Metallic and oxide liquid
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Published online ahead of print 24 Dec 2014

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Chemical Engineering Publications
Official 2015 Collection
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Citation counts: TR Web of Science Citation Count  Cited 13 times in Thomson Reuters Web of Science Article | Citations
Scopus Citation Count Cited 15 times in Scopus Article | Citations
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