Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage

Reichel, Florian, Clegg, Jack K., Gloe, Karsten, Gloe, Kerstin, Weigand, Jan J., Reynolds, Jason K., Li, Chun-Guang, Aldrich-Wright, Janice R., Kepert, Cameron J., Lindoy, Leonard F., Yao, Hong-Chang and Li, Feng (2014) Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage. Inorganic Chemistry, 53 2: 688-690. doi:10.1021/ic402686s

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Author Reichel, Florian
Clegg, Jack K.
Gloe, Karsten
Gloe, Kerstin
Weigand, Jan J.
Reynolds, Jason K.
Li, Chun-Guang
Aldrich-Wright, Janice R.
Kepert, Cameron J.
Lindoy, Leonard F.
Yao, Hong-Chang
Li, Feng
Title Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage
Formatted title
Self-assembly of an imidazolate-bridged FeIII/CuII heterometallic cage
Journal name Inorganic Chemistry   Check publisher's open access policy
ISSN 0020-1669
Publication date 2014-01-21
Year available 2014
Sub-type Article (original research)
DOI 10.1021/ic402686s
Open Access Status File (Author Post-print)
Volume 53
Issue 2
Start page 688
End page 690
Total pages 3
Place of publication Washington, DC, United States
Publisher American Chemical Society
Language eng
Formatted abstract
A rare, discrete, mixed-valent, heterometallic Fe(III)/Cu(II) cage, [Cu6Fe8L8](ClO4)12·χ solvent (H3L = tris{[2-{(imidazole-4-yl)methylidene}amino]ethyl} amine), was designed and synthesized via metal-ion-directed self-assembly with neutral tripodal metalloligands. The formation of this coordination cage was demonstrated by X-ray crystallography, ESI mass spectrometry, FT-IR, and UV-vis-NIR spectroscopy.
Keyword Chemistry, Inorganic & Nuclear
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2015 Collection
Official Audit
School of Chemistry and Molecular Biosciences
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Citation counts: TR Web of Science Citation Count  Cited 30 times in Thomson Reuters Web of Science Article | Citations
Scopus Citation Count Cited 32 times in Scopus Article | Citations
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Created: Tue, 18 Feb 2014, 10:36:32 EST by System User on behalf of School of Chemistry & Molecular Biosciences