Five discrete multinuclear metal-organic assemblies from one ligand: deciphering the effects of different templates

Riddell, Imogen A., Hristova, Yana R., Clegg, Jack K., Wood, Christopher S., Breiner Boris and Nitschke, Jonathan R. (2013) Five discrete multinuclear metal-organic assemblies from one ligand: deciphering the effects of different templates. Journal of the American Chemical Society, 135 7: 2723-2733. doi:10.1021/ja311285b


Author Riddell, Imogen A.
Hristova, Yana R.
Clegg, Jack K.
Wood, Christopher S.
Breiner Boris
Nitschke, Jonathan R.
Title Five discrete multinuclear metal-organic assemblies from one ligand: deciphering the effects of different templates
Journal name Journal of the American Chemical Society   Check publisher's open access policy
ISSN 0002-7863
1520-5126
Publication date 2013-02-20
Year available 2013
Sub-type Article (original research)
DOI 10.1021/ja311285b
Volume 135
Issue 7
Start page 2723
End page 2733
Total pages 11
Place of publication Columbus, OH, United States
Publisher American Chemical Society
Language eng
Formatted abstract
A rigid organic ligand, formed through the subcomponent self-assembly of p-toluidine and 6,6′-diformyl-3,3′-bipyridine, was employed in a systematic investigation into the synergistic and competing effects of metal and anion templation. A range of discrete and polymeric metal-organic complexes were formed, many of which represent structure types that have not previously been observed and whose formation would not be predicted on taking into account solely geometric considerations. These complex structures, capable of binding multiple guests within individual binding pockets, were characterized by NMR, ESI-MS, and single-crystal X-ray diffraction. The factors that stabilize individual complexes and lead to the formation of one over another are discussed.
Keyword Chemistry, Multidisciplinary
Chemistry
CHEMISTRY, MULTIDISCIPLINARY
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2014 Collection
School of Chemistry and Molecular Biosciences
 
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