Probing solvation in ionic liquids via the electrochemistry of the DPPH radical

Taylor, Alasdair W., Puttick, Simon and Licence, Peter (2012) Probing solvation in ionic liquids via the electrochemistry of the DPPH radical. Journal of the American Chemical Society, 134 38: 15636-15639. doi:10.1021/ja3052816


Author Taylor, Alasdair W.
Puttick, Simon
Licence, Peter
Title Probing solvation in ionic liquids via the electrochemistry of the DPPH radical
Journal name Journal of the American Chemical Society   Check publisher's open access policy
ISSN 0002-7863
1520-5126
Publication date 2012-09-01
Year available 2012
Sub-type Article (original research)
DOI 10.1021/ja3052816
Open Access Status
Volume 134
Issue 38
Start page 15636
End page 15639
Total pages 4
Place of publication Washington, DC United States
Publisher American Chemical Society
Language eng
Formatted abstract
The electrochemistry of the radical species 2,2-diphenyl-1-picrylhydrazyl, DPPH, has been studied in a range of common ionic liquids and its voltammetric response found to vary with the choice of anion. The trend observed is used to provide a relative Lewis basicity scale of nine ionic liquids commonly used as solvents
Keyword Redox Couple
Diphenylpicrylhydrazyl
Reactivity
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: Non HERDC
Australian Institute for Bioengineering and Nanotechnology Publications
 
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Created: Wed, 13 Nov 2013, 23:19:28 EST by Simon Puttick on behalf of Aust Institute for Bioengineering & Nanotechnology