Hydrogenation of olefins over hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex immobilized on functionalized MCM-41 and SBA-15

Joseph, Trissa, Deshpande, S. S., Halligudi, S. B., Vinu, A., Ernst, S. and Hartmann, M. (2003) Hydrogenation of olefins over hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex immobilized on functionalized MCM-41 and SBA-15. Journal of Molecular Catalysis A-Chemical, 206 1-2: 13-21. doi:10.1016/S1381-1169(03)00452-7


Author Joseph, Trissa
Deshpande, S. S.
Halligudi, S. B.
Vinu, A.
Ernst, S.
Hartmann, M.
Title Hydrogenation of olefins over hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex immobilized on functionalized MCM-41 and SBA-15
Journal name Journal of Molecular Catalysis A-Chemical   Check publisher's open access policy
ISSN 1381-1169
1873-314X
Publication date 2003-10-01
Sub-type Critical review of research, literature review, critical commentary
DOI 10.1016/S1381-1169(03)00452-7
Volume 206
Issue 1-2
Start page 13
End page 21
Total pages 9
Place of publication Amsterdam, Netherlands
Publisher Elsevier
Language eng
Formatted abstract
Hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex [RuHCl(CO)(PPh3)3] has been immobilized inside the pores of amine functionalized MCM-41 and SBA-15 materials. These grafted complexes were characterized by XRD, FTIR, N2 adsorption measurements, XPS and tested as catalyst for the hydrogenation of olefins. Immobilization and pore size has marked effects on the catalytic activity in the hydrogenation of olefins and the complex immobilized on functionalized SBA-15 was found to be catalytically more active than the one immobilized on MCM-41.
Keyword hydrido chlorocarbonyl tris-(triphenylphosphine) ruthenium(II) complex
MCM-41
SBA-15
Immobilization
Hydrogenation
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ

Document type: Journal Article
Sub-type: Critical review of research, literature review, critical commentary
Collection: Australian Institute for Bioengineering and Nanotechnology Publications
 
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