Electrochemical oxidation of reverse osmosis concentrate on boron-doped diamond anodes at circumneutral and acidic pH

Bagastyo, Arseto Yekti, Batstone, Damien J., Kristiana, Ina, Gernjak, Wolfgang, Joll, Cynthia and Radjenovic, Jelena (2012) Electrochemical oxidation of reverse osmosis concentrate on boron-doped diamond anodes at circumneutral and acidic pH. Water Research, 46 18: 6104-6112. doi:10.1016/j.watres.2012.08.038

Author Bagastyo, Arseto Yekti
Batstone, Damien J.
Kristiana, Ina
Gernjak, Wolfgang
Joll, Cynthia
Radjenovic, Jelena
Title Electrochemical oxidation of reverse osmosis concentrate on boron-doped diamond anodes at circumneutral and acidic pH
Journal name Water Research   Check publisher's open access policy
ISSN 0043-1354
Publication date 2012-09-05
Sub-type Article (original research)
DOI 10.1016/j.watres.2012.08.038
Volume 46
Issue 18
Start page 6104
End page 6112
Total pages 9
Place of publication London, United Kingdom
Publisher I W A Publishing
Language eng
Formatted abstract
Electrochemical processes have been widely investigated for degrading organic contaminants present in wastewater. This study evaluated the performance of electrochemical oxidation using boron-doped diamond (BDD) electrodes by forming OH▪ for the treatment of reverse osmosis concentrate (ROC) from secondary-treated wastewater effluents. Since oxidation by OH▪ and active chlorine species (HClO/ClO−) is influenced by pH, the electrochemical oxidation of ROC was evaluated at controlled pH 6-7 and at pH 1-2 (no pH adjustment). A high concentration of chloride ions in the ROC enhanced the oxidation, and 7-11% of Coulombic efficiency for chemical oxygen demand (COD) removal was achieved with 5.2 Ah L−1 of specific electrical charge. Complete COD removal was observed after 5.2 and 6.6 Ah L−1, yet the corresponding dissolved organic carbon (DOC) removal was only 48% (at acidic pH) and 59% (at circumneutral pH). Although a higher operating pH seemed to enhance the participation of OH▪ in oxidation mechanisms, high concentrations of chloride resulted in the formation of significant concentrations of adsorbable organic chlorine (AOCl) after electrochemical oxidation at both pH. While adsorbable organic bromine (AOBr) was degraded at a higher applied electrical charge, a continuous increase in AOCl concentration (up to 0.88 mM) was observed until the end of the experiments (i.e. 10.9 Ah L−1). In addition, total trihalomethanes (tTHMs) and total haloacetic acids (tHAAs) were further degraded with an increase in electrical charge under both pH conditions, to final total concentrations of 1 and 4 μM (tTHMs), and 12 and 22 μM (tHAAs), at acidic and circumneutral pH, respectively. In particular, tHAAs were still an order of magnitude above their initial concentration in ROC after further electrooxidation. Where high chloride concentrations are present, it was found to be necessary to separate chloride from ROC prior to electrochemical oxidation in order to avoid the formation of chlorinated by-products.
Keyword Adsorbable organic halogen
Boron doped diamond anode
Electrochemical oxidation
Reverse osmosis concentrate
Q-Index Code C1
Q-Index Status Confirmed Code
Institutional Status UQ
Additional Notes Available online 5 September 2012; In Press, Accepted Manuscript — Note to users;

Document type: Journal Article
Sub-type: Article (original research)
Collections: Official 2013 Collection
Advanced Water Management Centre Publications
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Created: Fri, 14 Sep 2012, 02:24:30 EST by Mr Arseto Bagastyo on behalf of Advanced Water Management Centre