Three-dimensional complex-shaped photopolymerized microparticles at liquid crystal interfaces

Martinez, Angel, Lee, Taewoo, Asavei, Theodor, Rubinsztein-Dunlop, Halina and Smalyukh, Ivan I. (2012) Three-dimensional complex-shaped photopolymerized microparticles at liquid crystal interfaces. Soft Matter, 8 8: 2432-2437. doi:10.1039/c2sm07125h


Author Martinez, Angel
Lee, Taewoo
Asavei, Theodor
Rubinsztein-Dunlop, Halina
Smalyukh, Ivan I.
Title Three-dimensional complex-shaped photopolymerized microparticles at liquid crystal interfaces
Journal name Soft Matter   Check publisher's open access policy
ISSN 1744-683X
1744-6848
Publication date 2012-01-01
Year available 2012
Sub-type Article (original research)
DOI 10.1039/c2sm07125h
Open Access Status Not Open Access
Volume 8
Issue 8
Start page 2432
End page 2437
Total pages 6
Place of publication Cambridge, United Kingdom
Publisher Royal Society of Chemistry
Language eng
Abstract Microparticles of arbitrary shapes immersed in the bulk of nematic fluids are known to produce dipolar or quadrupolar elastic distortions that can mediate long-range colloidal interactions. We use two-photon photopolymerization to obtain complex-shaped surface-bound microparticles that are then embedded into a nematic liquid crystal host with a uniform far-field director. By means of three-dimensional imaging with multi-photon excitation fluorescence polarizing microscopy, we demonstrate low-symmetry, long-range elastic distortions induced by the particles in the liquid crystal director field. These director distortions may provide a means for controlling elastic interactions in liquid crystals between custom-designed photopolymerized microparticles attached to confining solid substrates and nematic fluid-borne colloids, thus enabling elasticity-mediated templated self-assembly.
Keyword Chemistry, Physical
Materials Science, Multidisciplinary
Physics, Multidisciplinary
Polymer Science
Chemistry
Materials Science
Physics
Polymer Science
CHEMISTRY, PHYSICAL
MATERIALS SCIENCE, MULTIDISCIPLINARY
PHYSICS, MULTIDISCIPLINARY
POLYMER SCIENCE
Q-Index Code C1
Q-Index Status Confirmed Code
Grant ID DMR-0847782
Institutional Status UQ

Document type: Journal Article
Sub-type: Article (original research)
Collections: School of Mathematics and Physics
Official 2013 Collection
 
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