Organometallic silver(I) coordination polymers and supramolecular complexes based on novel multidentate thiophene- and benzenenitrile-containing symmetric and unsymmetric fulvene ligands

Dong, Yu-Bin, Geng, Yan, Ma, Jian-Ping and Huang, Ru-Qi (2006) Organometallic silver(I) coordination polymers and supramolecular complexes based on novel multidentate thiophene- and benzenenitrile-containing symmetric and unsymmetric fulvene ligands. Organometallics, 25 2: 447-462. doi:10.1021/om0507169


Author Dong, Yu-Bin
Geng, Yan
Ma, Jian-Ping
Huang, Ru-Qi
Title Organometallic silver(I) coordination polymers and supramolecular complexes based on novel multidentate thiophene- and benzenenitrile-containing symmetric and unsymmetric fulvene ligands
Journal name Organometallics   Check publisher's open access policy
ISSN 0276-7333
1520-6041
Publication date 2006-01-16
Year available 2005
Sub-type Article (original research)
DOI 10.1021/om0507169
Volume 25
Issue 2
Start page 447
End page 462
Total pages 16
Place of publication Washington, DC, United States
Publisher American Chemical Society
Language eng
Abstract Seven new conjugated symmetric and unsymmetric fulvene ligands L1−L7 were synthesized. Thirteen new organometallic coordination polymers and supramolecular complexes were obtained through self-assembly based on these new fulvene ligands in the benzene/toluene mixed solvent system. Compounds 1−13 have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The results indicate that the coordination chemistry of new fulvene ligands is versatile. They can adopt either a cis or a trans conformation to bind Ag(I) ion through not only the terminal −CN and thiophene functional groups but also the fulvene carbon atoms into organometallic coordination polymers or discrete complexes. In addition, the luminescent properties of L1, L3, L5, and L7 and some of their Ag(I) complexes were investigated preliminarily in EtOH and the solid state.
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Non-UQ
Additional Notes Publication Date (Web): December 14, 2005

Document type: Journal Article
Sub-type: Article (original research)
Collections: ERA 2012 Admin Only
School of Chemistry and Molecular Biosciences
 
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Created: Thu, 20 Oct 2011, 19:40:52 EST by Yan Geng on behalf of School of Chemistry & Molecular Biosciences