Simulation of Molecular Weight Distributions Obtained by Pulsed Laser Polymerization (PLP): New Analytical Expressions Including Intramolecular Chain Transfer to the Polymer

Nikitin, Anatoly N., Castignolles, Patrice, Charleux, Bernadette and Vairon, Jean-Pierre (2003) Simulation of Molecular Weight Distributions Obtained by Pulsed Laser Polymerization (PLP): New Analytical Expressions Including Intramolecular Chain Transfer to the Polymer. Macromolecular Theory and Simulations, 12 6: 440-448. doi:10.1002/mats.200350005


Author Nikitin, Anatoly N.
Castignolles, Patrice
Charleux, Bernadette
Vairon, Jean-Pierre
Title Simulation of Molecular Weight Distributions Obtained by Pulsed Laser Polymerization (PLP): New Analytical Expressions Including Intramolecular Chain Transfer to the Polymer
Journal name Macromolecular Theory and Simulations   Check publisher's open access policy
ISSN 1521-3919
1022-1344
Publication date 2003-07-01
Sub-type Article (original research)
DOI 10.1002/mats.200350005
Open Access Status Not yet assessed
Volume 12
Issue 6
Start page 440
End page 448
Total pages 9
Place of publication Zug, Switz
Publisher Wiley-VCH
Language eng
Subject 0303 Macromolecular and Materials Chemistry
Abstract A new approach for the simulation of PLP (pulsed laser polymerization) is presented. This approach allows one to obtain new analytical solutions for different polymerization schemes, including either chain transfer to the monomer or intramolecular chain transfer to the polymer. The first results of the simulation of PLP experiments on n-butyl acrylate at 20 °C and ambient pressure are presented.
Keyword backbiting
kinetics (polym.)
molecular weight distribution/molar mass distribution
pulsed laser polymerization
radical polymerization
Q-Index Code C1
Q-Index Status Provisional Code
Institutional Status Unknown

Document type: Journal Article
Sub-type: Article (original research)
Collections: Excellence in Research Australia (ERA) - Collection
Centre for Nutrition and Food Sciences Publications
 
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Citation counts: TR Web of Science Citation Count  Cited 30 times in Thomson Reuters Web of Science Article | Citations
Scopus Citation Count Cited 32 times in Scopus Article | Citations
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Created: Wed, 01 Apr 2009, 00:53:35 EST by Ms Julie Schofield on behalf of Centre for Nutrition and Food Sciences