Fluorinated-plasma modification of polyetherimide films

Kaba, M., Essamri, A., Mas, A., Schue, F., George, G. A., Cardona, F., Rintoul, L. and Wood, B. J. (2006) Fluorinated-plasma modification of polyetherimide films. Journal of Applied Polymer Science, 100 5: 3579-3588. doi:10.1002/app.22930


Author Kaba, M.
Essamri, A.
Mas, A.
Schue, F.
George, G. A.
Cardona, F.
Rintoul, L.
Wood, B. J.
Title Fluorinated-plasma modification of polyetherimide films
Journal name Journal of Applied Polymer Science   Check publisher's open access policy
ISSN 0021-8995
Publication date 2006
Sub-type Article (original research)
DOI 10.1002/app.22930
Volume 100
Issue 5
Start page 3579
End page 3588
Total pages 10
Place of publication Hoboken
Publisher John Wiley & Sons
Collection year 2006
Language eng
Subject C1
250502 Physical Chemistry of Macromolecules
780103 Chemical sciences
03 Chemical Sciences
0303 Macromolecular and Materials Chemistry
09 Engineering
0912 Materials Engineering
Abstract Ultem 1000 polyetherimide films prepared by cast-evaporating technique were covered with a 1H,1H,2H-tridecafluoro-oct-1-ene (PFO) plasma-polymerized layer. The effects of the plasma exposure time on the surface composition were studied by X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and surface energy analysis. The surface topography of the plasma layer was deduced from scanning electron microscopy. The F/C ratio for plasma-polymerized PFO under the input RF power of 50 W can be as high as 1.30 for 480 s and similar to 0.4-2 at % of oxygen was detected, resulting from the reaction of long-lived radicals in the plasma polymer with atmospheric oxygen. The plasma deposition of fluorocarbon coating from plasma PFO reduces the surface energy from 46 to 18.3 mJ m(-2). (c) 2006 Wiley Periodicals, Inc.
Keyword Plasma Polymerization
Fluoropolymer
X-ray Photoelectron Spectroscopy
Polyimide
Polymer Science
Low Dielectric-constant
Surface Fluorination
Polymerized Octofluorocyclobutane
Solid-surfaces
Membranes
Energy
Hexafluoropropylene
Spectroscopy
Gas
Q-Index Code C1

 
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Created: Wed, 15 Aug 2007, 08:46:19 EST