Geometric and electronic information from the spectroscopy of six-coordinate copper(II) compounds

Riley, Mark J. (2001). Geometric and electronic information from the spectroscopy of six-coordinate copper(II) compounds. In Hartmut Yersin (Ed.), Transition Metal and Rare Earth Compounds (pp. 57-80) Germany: Springer. doi:10.1007/3-540-44474-2_2


Author Riley, Mark J.
Title of chapter Geometric and electronic information from the spectroscopy of six-coordinate copper(II) compounds
Title of book Transition Metal and Rare Earth Compounds
Place of Publication Germany
Publisher Springer
Publication Year 2001
Sub-type Critical review of research, literature review, critical commentary
DOI 10.1007/3-540-44474-2_2
ISBN 3-540-67679-6
ISSN 0342-6793
Editor Hartmut Yersin
Volume number 214
Start page 57
End page 80
Total pages 24
Total chapters 3
Language eng
Subjects 250201 Transition Metal Chemistry
780103 Chemical sciences
B1
Abstract/Summary The ground and excited state geometry of the six-coordinate copper(II) ion is examined in detail using the CuF64- and Cu(H2O)(6)(2+) complexes as examples. A variety of spectroscopic techniques are used to illustrate the relations between the geometric and electronic properties of these complexes through the characterization of their potential energy surfaces.
Keyword Chemistry, Multidisciplinary
Copper(ii) Compounds
Jahn-teller Effect
Excited State Geometries
Jahn-teller Interactions
6-coordinate Copper(ii)
Host Lattices
Tuttons Salt
Complexes
Ion
Temperature
Spectrum
K2znf4
Model
Q-Index Code B1
Additional Notes ISSN: 0340-1022 (Print) 1436-5049 (Online)

Document type: Book Chapter
Collection: School of Chemistry and Molecular Biosciences
 
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Created: Tue, 14 Aug 2007, 10:54:18 EST