N-Substituent effect of maleimides on acrylate polymerization initiated by three-component systems

Clark, SC, Hill, DJT, Hoyle, CE, Jonsson, S, Miller, CW and Shao, LY (2003) N-Substituent effect of maleimides on acrylate polymerization initiated by three-component systems. Polymer International, 52 11: 1701-1710. doi:10.1002/pi.1296


Author Clark, SC
Hill, DJT
Hoyle, CE
Jonsson, S
Miller, CW
Shao, LY
Title N-Substituent effect of maleimides on acrylate polymerization initiated by three-component systems
Journal name Polymer International   Check publisher's open access policy
ISSN 0959-8103
Publication date 2003
Sub-type Article (original research)
DOI 10.1002/pi.1296
Volume 52
Issue 11
Start page 1701
End page 1710
Total pages 10
Place of publication United Kingdom
Publisher John Wiley
Collection year 2003
Language eng
Subject C1
250502 Physical Chemistry of Macromolecules
780103 Chemical sciences
Abstract In this paper, the relative photopolymerization efficiency for polymerization of a difunctional acrylate initiated by various N-substituted maleimides in the presence of amine and benzophenone are compared on the basis of a photo-differential scanning calorimetry (photo-DSC) study. The trends in the polymerization rates were obtained from the photopolymerization profiles and expressed in terms of a photoinitiation index, I-p. An N-substituent index, I-s, which indicates whether each N-substituent plays either a positive (when I-s > 1) or a negative (when I-s < 1) role in the initiation process relative to MI (unsubstituted maleimide), was determined. (C) 2003 Society of Chemical Industry.
Keyword Polymer Science
Photocuring
N-substituted Maleimide
Substitution Effect
Acrylate Polymerization
Mechanism
Radical Polymerization
Photopolymerization
Photoinitiators
Cyclohexylmaleimide
Copolymerization
Phenylmaleimide
Derivatives
Solvents
Q-Index Code C1

Document type: Journal Article
Sub-type: Article (original research)
Collections: 2004 Higher Education Research Data Collection
School of Chemistry and Molecular Biosciences
 
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Created: Wed, 15 Aug 2007, 01:56:42 EST